Double-Shell and Flower-Like ZnS-C3N4 Derived from in Situ Supramolecular Self-Assembly for Selective Aerobic Oxidation of Amines to Imines
Double-Shell and Flower-Like ZnS-C3N4 Derived from in Situ Supramolecular Self-Assembly for Selective Aerobic Oxidation of Amines to Imines
复制标题
原位超分子自组装双壳花状 ZnS-C3N4 用于胺选择性有氧氧化为亚胺
DOI：
10.1021/acssuschemeng.9b02969
复制
发表时间：
2019
影响因子：
8.4
通讯作者：
Yin Shuang-Feng
中科院分区：
文献类型：
--
作者：
Chen Peng;Meng Ling-Hu;Chen Lang;Guo Jun-Kang;Shen Sheng;Au Chak-Tong;Yin Shuang-Feng
多壳微纳米结构因其独特的性质而引起了广泛的研究关注。制造各个壳成分不同的复杂纳米结构的多壳中空结构是一个巨大的挑战。在此，通过简便的超分子自组装方法制备了双壳花状ZnS–C3N4(2-ZSCN)。由于其独特的结构，2-ZSCN在可见光照射下胺选择性有氧氧化为亚胺的过程中表现出增强的光催化活性和稳定性。
Multishelled micro-/nanostructures have attracted much research attention because of their unique properties. It is a big challenge to fabricate multishelled hollow structures of complex nanoarchitectures with the respective shells different in composition. Herein, the double-shell and flower-like ZnS–C3N4(2-ZSCN) was fabricated by a facile supramolecular self-assembly method. Because of its unique structure, 2-ZSCN exhibits enhanced photocatalytic activity and stability in the selective aerobic oxidation of amines to imines under visible-light irradiation.