FIRG024 - Enzymatic N2 activation: general discussion.

FIRG024 - Enzymatic N2 activation: general discussion.
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FIRG024 - 酶促 N2 激活:一般讨论。

DOI:
10.1039/d3fd90011h
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发表时间:
2023
影响因子:
3.4
通讯作者:
Abi Ghaida F
Abi Ghaida F
中科院分区:
化学2区
文献类型:
--
作者:
Abi Ghaida F

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Lance C.Seefeldt回答说:质子最终来自溶剂。目前还不完全清楚质子是如何被保持在活性中心进行底物还原的,但已经提出了一个或多个金属-辅基-桥联SulDes可能是质子的结合位置。
Lance C. Seefeldt answered: Protons ultimately come from the solvent. It is not fully known how the protons are held at the active site for delivery for substrate reduction, but it has been proposed that one or more of the metal-cofactorbridging sul des could be a binding site for protons.