Efficient and Z-selective cross-metathesis of conjugated enynes
Efficient and Z-selective cross-metathesis of conjugated enynes
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DOI：
10.1021/ol049378i
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发表时间：
2004-06-10
期刊：
影响因子：
5.2
通讯作者：
Lee, D
中科院分区：
文献类型：
--
作者：
Hansen, EC;Lee, D
用烯丙基醚作为分子内催化剂的载体，合成了共轭的炔基亚烷基。该中间体与烯烃和炔烃反应生成具有Z-选择性的共轭烯炔。
The generation of a conjugated alkynyl alkylidene has been achieved using an allyl ether moiety as an intramolecular catalyst delivery vehicle. The reaction of this intermediate with alkenes and alkynes yields conjugated enynes with Z-selectivity.