Incorporation of imidazole within the metal-organic framework UiO-67 for enhanced anhydrous proton conductivity
Incorporation of imidazole within the metal-organic framework UiO-67 for enhanced anhydrous proton conductivity
复制标题
在金属有机骨架 UiO-67 中掺入咪唑以增强无水质子电导率
DOI：
10.1039/c5dt01667c
复制
发表时间：
2015-01-01
影响因子：
4
通讯作者：
Liu, Yi
中科院分区：
文献类型：
--
作者：
Liu, Shucheng;Yue, Zifeng;Liu, Yi
采用蒸发法将咪唑引入金属-有机骨架UiO-67的通道中。imidazole@UiO-67复合材料在120℃无水条件下具有1.44 x 10(-3) S cm（-1）的高质子电导率。该杂化材料在高温下具有较低的活化能（0.36 eV），可视为超离子导体。
Imidazole was introduced into the channels of the metal-organic framework UiO-67 using an evaporation method. The imidazole@UiO-67 composite presents a high proton conductivity of 1.44 x 10(-3) S cm(-1) at 120 degrees C under anhydrous conditions. With a low activation energy at high temperatures (0.36 eV), the hybrid material can be regarded as a superionic conductor.