Recent Advances in the Syntheses of Aromatic Polyketones
Recent Advances in the Syntheses of Aromatic Polyketones
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芳香族聚酮的合成研究新进展
DOI：
10.5059/yukigoseikyokaishi.53.172
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发表时间：
1995
影响因子：
0.2
通讯作者：
N. Yonezawa
中科院分区：
文献类型：
--
作者：
N. Yonezawa
芳香族聚酮是一种性能优良的超级工程塑料。随着人们对聚合物结构和热行为的认识不断深入，近年来出现了许多新型芳香族聚酮，并采用了多种合成方法。本文从合成角度综述了近年来芳香族聚酮的研究进展。(1)为了获得高分子量的聚合物骨架，开发了新的合成反应，引入和去除临时辅助基团以保持聚合物链在链延伸反应中的柔性，以及使用过渡金属作为高效催化剂。(2)通过引入曲轴环和额外的共轭部分进行基本的结构扰动。(3)侧基的引入及其化学转化是为了实现新的结构和先进的性能。(4)精细的合成和反应设计的低聚物和聚合物前体的模型研究和反应性低聚/聚酮也进行了研究。1992年及以后的报告主要是调查。
Aromatic polyketone is one of the most highly performed super engineering plastics With the progress of clarification of the exact feature of structure and thermal behavior of the polymers, a lot of novel aromatic polyketones have appeared and various synthetic approaches were undertaken in these years The recent advances of polyketones are reviewed from synthetic interests. (1) New synthetic reactions, introduction and removal of tentative auxiliary groups in order to maintain the flexibility of polymer chain during chain elongation reaction, and uses of transition metals as a highly effective catalyst were developed for achievement of high-molecular-weight polymer skeleton. (2) Fundamental structural perturbation was undertaken by introduction of crankshaft rings and additional conjugated moieties. (3) Introduction of side groups and their chemical transformation were undertaken to perform new structures and advanced properties. (4) Fine syntheses and reactions of designed oligomers and polymer precursors both for model studies and reactive oligo/polyketones were also investigated. The reports in 1992 and later were mainly surveyed.