A new efficient route for the formation of quinoxaline N-oxides and N,N′-dioxides using HOF•CH3CN
A new efficient route for the formation of quinoxaline N-oxides and N,N′-dioxides using HOF•CH3CN
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DOI：
10.1021/jo0608016
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发表时间：
2006-07-21
影响因子：
3.6
通讯作者：
Rozen, Shlomo
中科院分区：
文献类型：
--
作者：
Carmeli, Mira;Rozen, Shlomo
HOF中心点CH3CN是一种很容易由氟和乙腈制备的高效氧转移剂，它与各种喹诺啉衍生物反应，在温和的条件和较短的反应时间内得到相应的单N-氧化物，特别是N，N'-二氧化物，收率很高。
HOF center dot CH3CN, a very efficient oxygen-transfer agent made readily from fluorine and aqueous acetonitrile, was reacted with various quinoxaline derivatives to give the corresponding mono N-oxides and especially the N,N'-dioxides in very good yields under mild conditions and short reaction times.