Efficient solar energy conversion using TiO2 nanotubes produced by rapid breakdown anodization -: a comparison

Efficient solar energy conversion using TiO2 nanotubes produced by rapid breakdown anodization -: a comparison
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DOI:
10.1002/pssr.200701074
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发表时间:
2007-07-01
影响因子:
2.8
通讯作者:
Schmuki, P.
Schmuki, P.
中科院分区:
物理与天体物理3区
文献类型:
--
作者:
Hahn, R.;Stergiooulus, T.;Schmuki, P.

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我们报道了不同TiO2纳米管层的染料敏化,它们的光电化学响应和太阳能转换效率。本研究中比较的管要么是在含氟电解质中控制钛阳极氧化,要么是在无氟电解质中快速击穿阳极氧化(RBA)。将不同的管层转化为锐钛矿并用ru染料(N719)敏化后,显然由RBA-NTs组成的管层比在自有序条件下形成的管具有更高的光响应和转换效率。
We report on dye-sensitization of different TiO2 nanotube layers, their photoelectrochemical response and their efficiency for solar energy conversion. The tubes compared in I this study were either grown by controlled Ti anodization in fluoride containing electrolytes or by rapid breakdown anodization (RBA) of Ti in fluoride free electrolytes. After converting the different tube layers to anatase and sensitizing with Ru-dye (N719), clearly layers consisting of RBA-NTs show a significantly higher photoresponse and conversion efficiencies than tubes formed under self-ordering conditions.