RAPID ELECTRONIC RELAXATION PHENOMENON IN THE TRANSITION BETWEEN 6A1 AND 2T2 STATES
RAPID ELECTRONIC RELAXATION PHENOMENON IN THE TRANSITION BETWEEN 6A1 AND 2T2 STATES
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6A1 和 2T2 状态之间过渡的快速电子弛豫现象
DOI：
10.1246/cl.1982.943
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发表时间：
1982
影响因子：
1.6
通讯作者：
Y. Takashima
中科院分区：
文献类型：
--
作者：
Y. Maeda;H. Ohshio;Y. Takashima
合成了N，N′-二（1-甲基-3-氧代亚丁基）乙二胺合-1，3-二-4-吡啶基丙烷合铁（III）四苯硼酸盐，测量了其穆斯堡尔谱和磁化率随温度的变化。通过穆斯堡尔谱学证实了6A 1和2 T2态之间的电子弛豫比57 Fe穆斯堡尔原子核激发态的寿命（0.86×10−7 s）快的事实。
N,N′-Bis(1-methyl-3-oxobutylidene)ethylenediaminato-1,3-di-4-pyridylpropaneiron(III) tetraphenylborate was synthesized and the temperature dependences of the Mossbauer spectrum and magnetic susceptibility for the compound were measured. The fact that the electronic relaxation between 6A1 and 2T2 states is faster than the lifetime (0.86×10−7 s) of the nuclear excited state of an 57Fe Mossbauer atom was confirmed by means of Mossbauer spectroscopy.