A Dehydrogenative Diels-Alder Reaction of Prenyl Derivatives with 2,3-Dichloro-5,6-dicyanobenzoquinone

A Dehydrogenative Diels-Alder Reaction of Prenyl Derivatives with 2,3-Dichloro-5,6-dicyanobenzoquinone
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DOI:
10.1002/adsc.201401038
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发表时间:
2015-03-23
影响因子:
5.4
通讯作者:
Zhou, Ling
Zhou, Ling
中科院分区:
化学2区
文献类型:
--
作者:
Feng, Hong-Xia;Wang, Yuan-Yuan;Zhou, Ling

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在温和的条件下,异戊二烯衍生物与2,3-二氯-5,6-二氰基苯醌(DDQ)发生了高效的双Diels-Alder(DHDA)反应,得到了一系列具有良好产率和非对映选择性的环己烯衍生物.
An efficient dehydrogenative Diels-Alder (DHDA) reaction of prenyl derivatives with 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) has been developed under mild conditions, leading to a series of cyclohexene derivatives with good to excellent yields and excellent diastereoselectivity.