Hydrogen storage in Zr-fumarate MOF
Hydrogen storage in Zr-fumarate MOF
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DOI：
10.1016/j.ijhydene.2015.06.109
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发表时间：
2015-09
影响因子：
7.2
通讯作者：
Jianwei Ren;N. Musyoka;Henrietta W. Langmi;B. North;M. Mathe;X. Kang;S. Liao
中科院分区：
文献类型：
--
作者：
Jianwei Ren;N. Musyoka;Henrietta W. Langmi;B. North;M. Mathe;X. Kang;S. Liao
本文以水为溶剂，甲酸为调节剂，合成了富马酸锆MOFs。从120 °C，24小时合成条件获得的高度结晶的富马酸锆MOF显示出高的热稳定性和水稳定性。与早期报道的MOF材料相比，更低的成本，更环保的合成工艺和相当的吸氢能力使富马酸锆MOF成为储氢应用的良好候选者。
In this work, we synthesized Zr-fumarate MOFs by applying water as solvent and formic acid as modulator. Highly crystalline Zr-fumarate MOF obtained from 120 °C, 24 h synthesis conditions showed high thermal and hydro stabilities. Compared to the early reported MOF materials, the lower cost, more environmentally friendly synthesis process and comparable hydrogen uptake capacity make Zr-fumarate MOFs a good candidate for hydrogen storage applications.