SURFACE-MODIFIED COBALT-BASED SENSOR AS A PHOSPHATE-SENSITIVE ELECTRODE
SURFACE-MODIFIED COBALT-BASED SENSOR AS A PHOSPHATE-SENSITIVE ELECTRODE
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DOI：
10.1021/ac00098a009
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发表时间：
1995-01-15
影响因子：
7.4
通讯作者：
YU, RQ
中科院分区：
文献类型：
--
作者：
XIAO, D;YUAN, HY;YU, RQ
研制了一种新型钴基磷酸根离子敏感电极。该电极对H_2PO_4~-具有相对选择性的电位响应，其电位响应可能来源于电极表面的CoO层。电极的响应机制进行了讨论的非化学计量的化合物CoO的主客体化学。
A new phosphate ion-sensitive electrode based on a cobalt matrix has been prepared. The electrode showed a relatively selective potentiometric response toward H2PO4- which seems to originate from the CoO layer covering the electrode surface. The response mechanism of the electrode is discussed in terms of the host-guest chemistry of a nonstoichiometric compound of CoO.