Study of the luminescence of tris(2-thenoyltrifluoroacetonato)lanthanide(III) complexes covalently linked to 1,10-phenanthroline-functionalized hybrid sol–gel glasses
Study of the luminescence of tris(2-thenoyltrifluoroacetonato)lanthanide(III) complexes covalently linked to 1,10-phenanthroline-functionalized hybrid sol–gel glasses
复制标题
DOI：
10.1016/j.jlumin.2004.12.001
复制
发表时间：
2005-07
影响因子：
3.6
通讯作者：
P. Lenaerts;Eline Ryckebosch;K. Driesen;R. V. Deun;P. Nockemann;C. Görller-Walrand;K. Binnemans
中科院分区：
文献类型：
--
作者：
P. Lenaerts;Eline Ryckebosch;K. Driesen;R. V. Deun;P. Nockemann;C. Görller-Walrand;K. Binnemans
通过将稀土络合物共价连接到溶胶-凝胶基质上，可以改善稀土络合物在Sol-Gel玻璃中的溶解度和均匀分布。在本研究中，几种稀土元素β-二酮配合物(Ln=Nd，Sm，Eu，Tb，Er，Yb)被固定在1，10-二氮杂菲功能化的溶胶-凝胶玻璃上。对于Eu(III)络合物，制备了一种具有聚合物性质的二乙氧基二甲基硅烷(DEDMS)溶胶-凝胶材料。对于其他稀土络合物，用四甲氧基硅烷(TMOS)和DEDMS为基质制备了溶胶-凝胶玻璃。这两个体系都是在中性反应条件下制备的。记录了高分辨发射光谱和激发光谱。测量了它们的发光寿命。
The solubility and uniform distribution of lanthanide complexes in sol–gel glasses can be improved by covalently linking the complexes to the sol–gel matrix. In this study, several lanthanide β-diketonate complexes (Ln=Nd, Sm, Eu, Tb, Er, Yb) were immobilized on a 1,10-phenanthroline functionalized sol–gel glass. For the europium(III) complex, a sol–gel material of diethoxydimethylsilane (DEDMS) with polymer-like properties was derived. For the other lanthanide complexes, the sol–gel glass was prepared by using a matrix of tetramethoxysilane (TMOS) and DEDMS. Both systems were prepared under neutral reaction conditions. High-resolution emission and excitation spectra were recorded. The luminescence lifetimes were measured.