Reductions Involving Unipositive Magnesium
Reductions Involving Unipositive Magnesium
复制标题
涉及单正镁的还原
DOI：
10.1021/cr50015a001
复制
发表时间：
1957
期刊：
影响因子：
62.1
通讯作者：
J. Kleinberg
中科院分区：
文献类型：
--
作者：
M. Rausch;W. E. Mcewen;J. Kleinberg
金属的还原作用是相当重要的。本审查关注的是使用镁所带来的减少，但特别是这种物质的单阳性形式。对文献的研究表明，这种还原主要分为两类：（a）通过阳极产生的单正性镁还原，和（B）用镁-卤化镁混合物还原。除了这些主题的讨论，对大量的镁的各种有机自由基离子所产生的单正性镁的影响进行了描述。
Reductions effected by metals are of considerable significance. The present review is concerned with reductions brought about by the use of magnesium, but specifically with the unipositive form of this substance. Examination of the literature reveals that such reductions fallinto two main categories:(a) those by means of unipositive magnesium anodically generated, and (b) reductions with magnesium-magnesium halide mixtures. In addition to a discussion of these topics, the effects on massive magnesium of a variety of organic radical-ions generated by unipositive magnesium are described.