Metal-Rich Metal-Metalloid Phases
Metal-Rich Metal-Metalloid Phases
复制标题
富金属金属-非金属相
DOI：
10.1007/978-1-4899-5564-7_6
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发表时间：
1969
期刊：
影响因子：
--
通讯作者：
H. Stadelmaier
中科院分区：
文献类型：
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作者：
H. Stadelmaier
这是对过渡元素的硼化物、碳化物、氮化物和氧化物的综述，通常与非过渡元素结合使用。在富含金属的化合物中，类金属原子是孤立的，并被六个或八个彼此紧密接触的过渡金属原子包围。因此，准金属原子是填隙的，有时在严格意义上，相场包括不含准金属（“未填充”）的成分。挑选出五种结构类型是因为它们广泛出现并且作者通过自己的工作熟悉了它们。最初可能有人反对将硼化物、碳化物、氮化物和氧化物归为一类。找到涵盖从硼化物到氧化物整个范围的单独结构类型确实很少见，但并非不可能。另一方面，类型之间有太多重叠，以至于共同的分类似乎是合理的。
This is a review of borides, carbides, nitrides, and oxides of transition elements, often in combination with non-transitional elements. In the metal rich compounds the metalloid atom is isolated and surrounded by six or eight transition metal atoms in close contact with each other. The metalloid atom is therefore interstitial, sometimes in the strict sense that the phase fields include metalloid-free (" unfilled") compositions. Five structure types are singled out because they occur extensively and because the author is familiar with them through his own work. There may be some initial objection to having borides, carbides, nitrides, and oxides lumped together in one class. It is indeed rare, but not impossible, to find an individual structure type that spans the entire range from borides to oxides. On the other band, there is so much overlap between types that a common classification does seem justified.