Asymmetric dinuclear bis(dipyrrinato)zinc(II) complexes: broad absorption and unidirectional quantitative exciton transmission

Asymmetric dinuclear bis(dipyrrinato)zinc(II) complexes: broad absorption and unidirectional quantitative exciton transmission
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DOI:
10.1039/c4cc01573h
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发表时间:
2014-01-01
影响因子:
4.9
通讯作者:
Nishihara, Hiroshi
Nishihara, Hiroshi
中科院分区:
化学2区
文献类型:
--
作者:
Tsuchiya, Mizuho;Sakamoto, Ryota;Nishihara, Hiroshi

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合成了不对称杂配双核双(二吡啶)锌(II)配合物,并证明其可以收集跨紫外和可见光区域(340-655 nm)的各种光。这些配合物还在其结构中从一端传输到另一端,光谱研究证明了定量和快速的能量转移。
Asymmetric, heteroleptic dinuclear bis(dipyrrinato)zinc(II) complexes were synthesized and demonstrated to collect a wide range of light across the UV and visible regions (340-655 nm). The complexes also conveyed excitons across their structure from one end to the other, with spectroscopic studies demonstrating quantitative and fast energy transfer.