Breakdown Pattern of Hydrocarbons by Laser Breakdown Time-of-flight Mass Spectrometry

Breakdown Pattern of Hydrocarbons by Laser Breakdown Time-of-flight Mass Spectrometry
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激光击穿飞行时间质谱法分析碳氢化合物的击穿模式

DOI:
10.1080/00387010.2014.959135
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发表时间:
2015-06
影响因子:
1.7
通讯作者:
JI PING LIU
JI PING LIU
中科院分区:
化学4区
文献类型:
--
作者:
ZHEN ZHEN WANG;YOSHIHIRO DEGUCHI;JUN JIE YAN;JI PING LIU

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开发了激光击穿飞行时间质谱法,并应用于检测碳氢化合物的击穿模式,这对于提高颗粒和碳氢化合物等各种混合物中重金属化合物的可检测性具有重要意义。使用1064、532和266 nm激光输出评价该方法的激光波长依赖性。使用1064和532 nm输出的击穿过程显示出对各种重金属检测的碎片干扰较小。该方法适用于各种烃类,它表明了使用的模式分解产物的烃类分类的可能性。
The laser breakdown time-of-flight mass spectrometry was developed and applied to detect the breakdown patterns of hydrocarbons that are significant to improve the detectability of heavy metals compounded in various mixtures such as particles and hydrocarbons. The laser wavelength dependence of this method was evaluated using 1064, 532, and 266 nm laser outputs. Breakdown processes using 1064 and 532 nm outputs showed less interference of fragmentation for the detection of various heavy metals. The method was applied to various hydrocarbons and it showed the possibility of categorization of hydrocarbon groups using the pattern of breakdown products.
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