Magic numbers in sims of Mn similar to those of charged Ar clusters

Magic numbers in sims of Mn similar to those of charged Ar clusters
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Mn 的 sims 中的幻数与带电 Ar 团簇的幻数相似

DOI:
10.1007/bf01448288
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发表时间:
1991
期刊:
Zeitschrift für Physik D Atoms, Molecules and Clusters
影响因子:
--
通讯作者:
I. Katakuse
I. Katakuse
中科院分区:
--
文献类型:
--
作者:
Y. Saito;Hiroyuki Ito;I. Katakuse

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用7 keV的正离子轰击产生了锰团簇离子Mnk ~+(k = 60),用双聚焦质谱仪进行了分析。在k =5,14,16,29,34,45和54处发现强度的不连续变化。这些幻数中的大多数与在方舟+中观察到的幻数一致或仅相差一个。Mn ~(k+)和方舟~(k+)幻数的相似性表明,带电Mn团簇与带电Ar团簇的成键性质相似,团簇中心的正离子与周围中性原子之间的极化力是主要的结合力.
Manganese cluster ions Mnk+ (k≲60) have been produced by 7 keV Xe ion bombardment and analyzed by a double-focusing mass spectrometer. Discontinuous variations of intensity are found atk=5, 14, 16, 29, 34, 45 and 54. Most of these magic numbers coincide with or differ by only one from those observed in Ark+. The similarity in magic numbers between Mnk+ and Ark+ indicates that the bonding nature in the charged Mn clusters is similar to that in the charged Ar clusters; The polarization force between a positive ion in the center of a cluster and surrounding neutral atoms is dominant binding force.