Copper-Catalyzed Hydroboration of Carbon Dioxide
Copper-Catalyzed Hydroboration of Carbon Dioxide
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DOI：
10.1021/om400175h
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发表时间：
2013-04
期刊：
影响因子：
2.8
通讯作者：
R. Shintani;K. Nozaki
中科院分区：
文献类型：
--
作者：
R. Shintani;K. Nozaki
本文研究了铜/N-杂环卡宾催化二氧化碳硼氢化反应，在温和条件下选择性地合成甲酸衍生物。已经进行了针对理解该过程的催化循环的调查，并且硼氢化产物可以直接用作各种胺的氢化试剂。
A copper/N-heterocyclic carbene catalyzed hydroboration of carbon dioxide has been developed to give a formic acid derivative selectively under mild conditions. Investigations directed toward understanding the catalytic cycle of this process have been carried out, and the hydroboration product can be directly used as a formylation reagent for various amines.