A Highly Stable Nanotubular MOF Rotator for Selective Adsorption of Benzene and Separation of Xylene Isomers
A Highly Stable Nanotubular MOF Rotator for Selective Adsorption of Benzene and Separation of Xylene Isomers
复制标题
用于选择性吸附苯和分离二甲苯异构体的高度稳定的纳米管 MOF 旋转器
DOI：
10.1021/acs.inorgchem.5b01581
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发表时间：
2015-11-16
影响因子：
4.6
通讯作者：
Kirillov, Alexander M.
中科院分区：
文献类型：
--
作者：
Huang, Wei;Jiang, Jun;Kirillov, Alexander M.
在溶剂热条件下制备了具有六角形通道和罕见的 ptr 拓扑结构的非常稳定的管状 3D Zn-MOF，用于 C6-8 芳香族化合物的液相和气相吸附和分离。该材料对苯表现出优先的亲和力，并且可以在环境条件下以气相和液相有效地将苯与其有机类似物分离。此外，它表现出比其他 C8 二甲苯更好的对二甲苯吸收。
A remarkably stable tubular 3D Zn-MOF with hexagonal channels and a rare ptr topology was prepared under solvothermal conditions for liquid and vapor phase adsorption and separation of the C6-8 aromatic compounds. The material showed preferential affinity for benzene and can effectively separate benzene from its organic analogues under ambient conditions in both vapor and liquid phases. Furthermore, it exhibited preferable uptake of p-xylene over other C8 xylenes.