[Zn2(H2O)3(2,2′-bipy)2(btc)][Zn(H2O)(2,2′-bipy)(btc)]•8H2O:: a novel zinc-carboxylate complex consisting of independently cationic and anionic chains
[Zn2(H2O)3(2,2′-bipy)2(btc)][Zn(H2O)(2,2′-bipy)(btc)]•8H2O:: a novel zinc-carboxylate complex consisting of independently cationic and anionic chains
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DOI：
10.1016/s1387-7003(03)00145-x
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发表时间：
2003-07-01
影响因子：
3.8
通讯作者：
Hong, MC
中科院分区：
文献类型：
--
作者：
Li, XJ;Sun, DF;Hong, MC
一种新型锌配合物[Zn-2（H2O）（3）]（2，2'-bipy）（2）（btc）][Zn（H2O）以H（3）btc、Zn（CH_3CO_2）（2）·2 H（2）O和2为原料，通过水热反应合成了[（2，2 ′-bipy）（btc）]·8H（2）O（1），（H（3）btc = 1，3，5-苯三甲酸，2，2 ′-bipy = 2，2 ′-联吡啶），2-联吡啶在180 ℃下进行，并通过单晶X射线衍射分析进行表征。络合物I由独立的阳离子和阴离子链组成。链间的氢键相互作用扩展成二维超分子结构。(C)2003 Elsevier Science B. V.保留所有权利。
A novel zinc complex, [Zn-2(H2O)(3) (2,2'-bipy)(2)(btc)][Zn(H2O)(2, 2'-bipy)(btc)].8H(2)O (1), (H(3)btc = 1,3,5- benzenetricarboxylic acid, 2,2'-bipy = 2,2'-bipyridine) has been prepared by hydrothermal reaction of H(3)btc, Zn(CH3CO2)(2).2H(2)O and 2,2-bipyridine at 180 degreesC and characterized by single-crystal X-ray diffraction analysis. Complex I consists of independently cationic and anionic chains. The hydrogen bonding interactions between chains extend I into a two-dimensional supramolecular architecture. (C) 2003 Elsevier Science B.V. All rights reserved.