Electroreduction Behavior of Dinitrogen over Ruthenium Cathodic Catalyst

Electroreduction Behavior of Dinitrogen over Ruthenium Cathodic Catalyst
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二氮在钌阴极催化剂上的电还原行为

DOI:
10.1246/cl.2003.440
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发表时间:
2003
期刊:
影响因子:
1.6
通讯作者:
Shou
Shou
中科院分区:
化学4区
文献类型:
--
作者:
Shu;Xiu;Zuo;Y. Kong;Shou

文献摘要

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在室温和常压下,在钌催化剂的水溶液中,用电化学方法还原二氮。结果表明,活性炭负载的化学沉积钌是一种有效的催化剂,具有良好的活性和稳定性。在差分线性扫描伏安图中首次观察到一个多肩峰,对应于二氮还原为氨。
Dinitrogen was reduced electrochemically at ambient temperature and pressure in aqueous solution over ruthenium catalyst. It was found that the chemically deposited ruthenium loaded on active carbon was an effective catalyst with good activity and stability for nitrogen reduction. A peak with many shoulders corresponding to the reduction of dinitrogen to ammonia was first observed in the difference linear sweep voltammogram.