The growth of single crystal silver wires at the nitrobenzene|water interface.
The growth of single crystal silver wires at the nitrobenzene|water interface.
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DOI：
10.1039/c0cp01469a
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发表时间：
2011-06
期刊：
影响因子：
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通讯作者：
U. Hasse;G. Palm;W. Hinrichs;J. Schäfer;F. Scholz
中科院分区：
文献类型：
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作者：
U. Hasse;G. Palm;W. Hinrichs;J. Schäfer;F. Scholz
当溶解在水相中的银离子被溶解在硝基苯相中的十甲基二茂铁还原时，可以在硝基苯水界面生长单晶银线。这些线的成功生长取决于许多实验条件，最重要的是反应物的浓度比、成核速率、形成的核的形状和核的润湿性。尺寸-时间依赖性可以根据银核和线的微电极行为进行建模。 AFM、SEM、光学显微镜和单晶 X 射线衍射已用于研究银核和银线的形态。
Single crystal silver wires can be grown at the nitrobenzene|water interface when silver ions dissolved in the aqueous phase are reduced by decamethyl ferrocene dissolved in the nitrobenzene phase. The successful growth of these wires depends on a number of experimental conditions, most prominently on the concentration ratio of reactants, nucleation rates, shape of formed nuclei, and wettability of nuclei. The size-time dependence can be modeled on the basis of microelectrode behavior of the silver nuclei and wire. AFM, SEM, light microscopy and single crystal X-ray diffraction has been applied to study the morphology of the silver nuclei and wires.