FeO⊕ Activates Methane
FeO⊕ Activates Methane
复制标题
DOI：
10.1002/anie.199014331
复制
发表时间：
1990-12
影响因子：
--
通讯作者：
D. Schröder;H. Schwarz
中科院分区：
文献类型：
--
作者：
D. Schröder;H. Schwarz
- 其中主要形成FeOH + CH和FeOH + CH 3OH。然而，该反应比之前的通信中描述的慢四倍;然而，催化活化的机会并不坏，因为在通过N2 O还原消除的过程中从中间体1再生的Fe的氧化物可以容易地重新引入循环中用于进一步的反应。
—whereby predominantly FeOH⊕+ CHand Fe⊕+ CH3OH are formed. This reaction is, however, four times slower than that described in the previous communication; nevertheless, the chances for a catalytic activation are not bad, since the Fe⊕regenerated from the intermediate1during the course of the reductive elimination by N2O can easily be reintroduced in the cycle for further reaction.