Bis-Tris Propane as a New Polydentate Linker in the Synthesis of Iron(III) and Manganese(II/III) Complexes
Bis-Tris Propane as a New Polydentate Linker in the Synthesis of Iron(III) and Manganese(II/III) Complexes
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DOI：
10.1021/ic8015386
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发表时间：
2008-11-03
影响因子：
4.6
通讯作者：
Murrie, Mark
中科院分区：
文献类型：
--
作者：
Ferguson, Alan;Darwish, Amiera;Murrie, Mark
我们描述了两个新的配合物的合成，结构和磁性，一个十核铁（III）簇和一个六核混价锰（II/III）簇，其中以前未开发的多齿配体双-三丙烷{(CH2OH)(3)CNH(CH2)(3)NHC(CH2OH)(3)}被用来连接小簇碎片成高核配合物。
We describe the synthesis, structure, and magnetic properties of two new complexes, one decanuclear iron(III) cluster and one hexanuclear mixed-valence manganese(II/III) cluster, where the previously unexplored polydentate ligand Bis-tris propane {(CH2OH)(3)CNH(CH2)(3)NHC(CH2OH)(3)} is used to link small cluster fragments into high-nuclearity complexes.