Mixed ethyl bromide and ethyl chloride pyrolyses
Mixed ethyl bromide and ethyl chloride pyrolyses
复制标题
溴乙烷和氯乙烷混合热解
DOI：
10.1039/tf9666201560
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发表时间：
1966
影响因子：
--
通讯作者：
R. A. Ross
中科院分区：
文献类型：
--
作者：
N. Capon;R. A. Ross
溴乙烷在气相中的无阻热解级数已被证实为1.5。混合热解的氯乙烷和溴乙烷，无论是在存在和不存在的环己烯，是一致的氯乙烷和最大限度地抑制溴乙烷分解是分子。对氯乙烷的分解进行了重新研究。在419.4-499.1°温度范围内的速率方程为log 10 k 1 = 13.46- 56，620/2.303 RT（sec-1）。
The order of the uninhibited pyrolysis of ethyl bromide in the gas phase has been confirmed as 1.5. Mixed pyrolyses of ethyl chloride and ethyl bromide, both in the absence and presence of cyclohexene, are consistent with the ethyl chloride and the maximally inhibited ethyl bromide decompositions being molecular. The decomposition of ethyl chloride has been re-investigated. The rate equation over the temperature range 419.4-499.1° was log10k1= 13.46–56,620/2.303 RT(sec–1).