Stereocontrolled Synthesis of Paracentrone
Stereocontrolled Synthesis of Paracentrone
复制标题
Paracentrone 的立体控制合成
DOI：
10.1055/s-0036-1588906
复制
发表时间：
2017
期刊：
影响因子：
2
通讯作者：
K. Sakaguchi
中科院分区：
文献类型：
--
作者：
Y. Nishioka;Y. Yano;N. Kinashi;N. Oku;Y. Toriyama;S. Katsumura;T. Shinada;K. Sakaguchi
通过C5硼酸酯和碘取代二烯的顺序交叉偶联反应，实现了C31类胡萝卜素侧心酮的立体控制全合成。C5硼酸酯和碘取代二烯是新开发的共轭多烯体系两端延伸的构筑块。
The stereocontrolled total synthesis of the C31 apocarotenoid paracentrone was achieved by sequential cross-coupling reactions using C5 boronic acid ester and iodo-substituted dienes, which were newly developed building blocks for elongation of the conjugated polyene systems at both their terminals.