alpha-SUBSTITUTED UNSYMMETRICAL PHTHALOCYANINES WITH ONE THROUGH THREE TTF UNITS AND THEIR OPTICAL AND ELECTROCHEMICAL PROPERTIES
alpha-SUBSTITUTED UNSYMMETRICAL PHTHALOCYANINES WITH ONE THROUGH THREE TTF UNITS AND THEIR OPTICAL AND ELECTROCHEMICAL PROPERTIES
复制标题
具有一到三个TTF单元的α-取代的不对称酞菁及其光学和电化学性质
DOI：
10.1080/10426507.2012.729115
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发表时间：
2013
期刊：
影响因子：
0.6
通讯作者：
Takeshi Kimura
中科院分区：
文献类型：
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作者：
遠堂 敬史;土井 貴弘;分島 亮;日夏 幸雄;大久保貴弘,遠藤恆平,柴田 高 範;Takeshi Kimura
由具有 TTF 单元的 3,6-二辛基邻苯二甲腈 (1)、4,5-二辛氧基邻苯二甲腈 (2) 和 3,6-二辛氧基邻苯二甲腈 (3) 制备四硫氟瓦烯 (TTF) 环状对称和不对称酞菁 (4)、(5) 和 (6)。四-TTF-环化酞菁 (4) 和碘产生电子转移络合物，该络合物显示出自由基阳离子特性。
Tetrathiafluvalene (TTF)-annulated symmetrical and unsymmetrical phthalocyanines (4), (5), and (6) were prepared from 3,6-dioctylphthalonitrile (1) with a TTF unit, 4,5-dioctyloxyphthalonitrile (2), and 3,6-dioctyloxyphthalonitrile (3). Tetra-TTF-annulated phthalocyanine (4) and iodine produced an electron transfer complex which showed a radical cationic character.