Acetylenes Rearranging on Ruthenium-Porphyrinogen and Leading to Vinylidene and Carbene Functionalities.

Acetylenes Rearranging on Ruthenium-Porphyrinogen and Leading to Vinylidene and Carbene Functionalities.
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乙炔在钌卟啉原上重排并产生亚乙烯基和卡宾官能团。

DOI：
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发表时间：
2001
期刊：
Angewandte Chemie
影响因子：
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通讯作者：
C. Floriani
C. Floriani
中科院分区：
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文献类型：
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作者：
L. Bonomo;Christine Stern;E. Solari;R. Scopelliti;C. Floriani

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通过质子转移反应，卟啉原协助末端乙炔转化为Ru-亚乙烯基，这是各种Ru-卡宾和Ru-累积多烯的入口点。该方案（其中卟啉原是程式化的）显示了可逆的相互转化的乙炔成二亚乙烯基单位。
Through a proton-transfer reaction a porphyrinogen assists the transformation of terminal acetylenes into Ru-vinylidenes, which are the entry point to a variety of Ru-carbenes and Ru-cumulenes. The scheme (in which the porphyrinogen is stylized) shows the reversible interconversion of an acetylide into a divinylidene unit.