The formyl C-H--O hydrogen bond as a critical factor in enantioselective reactions of aldehydes .4. Aldol, ethylation, hydrocyanation and Diels-Alder reactions catalyzed by chiral B, Ti and Al Lewis acids.

The formyl C-H--O hydrogen bond as a critical factor in enantioselective reactions of aldehydes .4. Aldol, ethylation, hydrocyanation and Diels-Alder reactions catalyzed by chiral B, Ti and Al Lewis acids.
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DOI:
10.1016/s0040-4039(97)00932-5
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发表时间:
1997-06-23
影响因子:
1.8
通讯作者:
Lee, TW
Lee, TW
中科院分区:
化学4区
文献类型:
--
作者:
Corey, EJ;BarnesSeeman, D;Lee, TW

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甲酰基 C-H-O 氢键为醛的几种不同催化对映选择性加成反应提供了合理的解释,如图 1-5 所示。 (C) 1997 爱思唯尔科学有限公司。
Formyl C-H-O hydrogen bonding provides a rational explanation of several diverse catalytic enantioselective addition reactions of aldehydes, as outlined in Figures 1-5. (C) 1997 Elsevier Science Ltd.