Synthesis of Functionalized 2,3,4,5-Tetraphenylsilole Derivatives Through Hydrosilylation and Their Crystal Structures
Synthesis of Functionalized 2,3,4,5-Tetraphenylsilole Derivatives Through Hydrosilylation and Their Crystal Structures
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DOI：
10.1080/00397911.2011.555049
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发表时间：
2012-04
影响因子：
2.1
通讯作者：
Yunsheng Zhang;Shuhong Li;Rui Wang;Li-Min Chen;Caihong Xu
中科院分区：
文献类型：
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作者：
Yunsheng Zhang;Shuhong Li;Rui Wang;Li-Min Chen;Caihong Xu
摘要通过1-甲基-2，3，4，5-四苯基-1H-硅烷与对乙炔苯衍生物的硅氢化反应，高产率地合成了一系列新的功能化2，3，4，5-四苯基硅烷。这种合成提供了一种在硅胶中引入反应性引电子或给电基的简便方法。所有新的硅沸石都表现出聚集诱导发射(AIE)效应。图形摘要
Abstract A series of new functionalized 2,3,4,5-tetraphenylsiloles were successfully synthesized in good yields by hydrosilylation reaction of 1-methyl-2,3,4,5-tetraphenyl-1H-silole with p-ethynyl benzene derivatives. This synthesis provides a convenient method of introducing reactive electron-withdrawing or electro–donating groups into siloles. All new siloles show aggregation-induced emission (AIE) effects. GRAPHICAL ABSTRACT