Formation of an interlocked double-chain from an organic-inorganic [2]rotaxane.
Formation of an interlocked double-chain from an organic-inorganic [2]rotaxane.
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DOI：
10.1039/c8cc09339c
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发表时间：
2019-03
影响因子：
4.9
通讯作者：
J. Ferrando‐Soria;Antonio Fernandez;I. Vitorica-Yrezabal;Deepak Asthana;C. Muryn;F. Tuna;G. Timco-
中科院分区：
文献类型：
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作者：
J. Ferrando‐Soria;Antonio Fernandez;I. Vitorica-Yrezabal;Deepak Asthana;C. Muryn;F. Tuna;G. Timco-
在这里，我们证明了含有聚合联锁菊花链的结构是通过无机-有机[2]轮烷[HB{CrIII7NiII(μ-F)8(O2CtBu)16}]的反应获得的，其中B是以联吡啶单元封端的有机线，具有以氧为中心的金属羧酸盐三角形[FeIII2CoII(μ3-O)(O2CtBu)6(HO2CtBu)3]。
Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic-organic [2]rotaxane [HB{CrIII7NiII(μ-F)8(O2CtBu)16}], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2CoII(μ3-O)(O2CtBu)6(HO2CtBu)3].