The synthesis and molecular structure of a disilacyclopropanimine

The synthesis and molecular structure of a disilacyclopropanimine
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二硅杂环丙胺的合成及分子结构

DOI:
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发表时间:
1987
期刊:
影响因子:
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通讯作者:
R. West
R. West
中科院分区:
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文献类型:
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作者:
H. Yokelson;A. Millevolte;K. Haller;R. West

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四(2,6-二甲基苯基)二二烯在室温下与(2,6-二甲基苯基)异氰化物在苯溶液中反应生成二硅环丙胺(1),一种亮红色结晶化合物,λmax=;510nm,通过x射线晶体学确定了其结构。
Tetra(2,6-dimethylphenyl)disilene reacts with (2,6-dimethylphenyl)isocyanide in benzene solution at room temperature to form disilacyclopropanimine (1), a bright red crystalline compound with λmax=; 510nm, whose structure was established by X-ray crystallography.