Transformation of RN=CHPh to R(R′3Si)NCH2Ph in the Catalytic Desulfurization of Secondary Thioamide with R′3SiH Promoted by an Iron Complex
Transformation of RN=CHPh to R(R′3Si)NCH2Ph in the Catalytic Desulfurization of Secondary Thioamide with R′3SiH Promoted by an Iron Complex
复制标题
DOI：
10.1002/hc.21175
复制
发表时间：
2014-11
影响因子：
0.3
通讯作者：
Kozo Fukumoto;Akane Sakai;T. Murai;H. Nakazawa
中科院分区：
文献类型：
--
作者：
Kozo Fukumoto;Akane Sakai;T. Murai;H. Nakazawa
在CpFe(CO)2Me(1)存在下，亚胺（RN=CHPh）与氢硅烷（R ' 3SiH）反应生成硅氢化产物R(R ' 3Si)NCH2Ph。这一发现有助于我们了解1催化仲硫酰胺脱硫的反应机理，得到相应的亚胺和胺分别作为主产物和副产物。
The reaction of imine (RN=CHPh) with hydrosilane (R′3SiH) in the presence of CpFe(CO)2Me (1) revealed the formation of a hydrosilylation product (R(R′3Si)NCH2Ph). The findings helped us to understand the reaction mechanism of desulfurization of secondary thioamide catalyzed by 1 to give the corresponding imine and amine as a major and minor product, respectively.