Fluorinated free radicals
Fluorinated free radicals
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氟化自由基
DOI：
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发表时间：
1998
期刊：
影响因子：
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通讯作者：
W. Dolbier
中科院分区：
文献类型：
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作者：
W. Dolbier
介绍了溶液中含氟碳基自由基的结构、反应性和化学的各个方面。讨论了氟取代基对自由基结构、稳定性和电负性的影响。总结了氟化自由基的产生方法。对全氟正烷基、支链全氟烷基和部分氟化自由基对烯烃加成、H 原子夺取和分子内重排反应的反应性进行了批判性分析。最后，总结了氟化自由基的合成有用化学。
All aspects of the structure, reactivity and chemistry of fluorine-containing, carbon-based free radicals in solution are presented. The influence of fluorine substituents on the structure, the stability and the electronegativity of free radicals is discussed. The methods of generation of fluorinated radicals are summarized. A critical analysis of the reactivities of perfluoro-n-alkyl, branched chain perfluoroalkyl and partially-fluorinated free radicals towards alkene addition, H-atom abstraction, and towards intramolecular rearrangement reactions is presented. Lastly, a summary of the synthetically-useful chemistry of fluorinated radicals is presented.