Polymerization of an optically active phenylacetylene derivative bearing an azide residue by click reaction and reaction with a rhodium catalyst
Polymerization of an optically active phenylacetylene derivative bearing an azide residue by click reaction and reaction with a rhodium catalyst
复制标题
DOI：
10.1039/b806343e
复制
发表时间：
2008-01-01
影响因子：
4.9
通讯作者：
Yashima, Eiji
中科院分区：
文献类型：
--
作者：
Kobayashi, Shinzo;Itomi, Ken;Yashima, Eiji
本文提出了一种合成具有不同骨架结构的多种光学活性聚合物的简便方法，该方法是通过铑催化剂聚合带有乙炔单元的光学活性芳族叠氮化物，然后进行悬挂叠氮化物的咔嗒反应或单体的咔嗒聚合。
A facile method for synthesizing diverse optically active polymers with different backbone structures was developed by the polymerization of an optically active aromatic azide bearing an acetylene unit with a rhodium catalyst followed by the click reaction of the pendant azides or by the click polymerization of the monomer.