Deoxygenative coupling of nitroarenes for the synthesis of aromatic azo compounds with CO using supported gold catalysts
Deoxygenative coupling of nitroarenes for the synthesis of aromatic azo compounds with CO using supported gold catalysts
复制标题
使用负载金催化剂进行硝基芳烃脱氧偶联与 CO 合成芳香偶氮化合物
DOI：
10.1039/c5cc03134f
复制
发表时间：
2015-01-01
影响因子：
4.9
通讯作者：
Cao, Yong
中科院分区：
文献类型：
--
作者：
Li, Hai-Qian;Liu, Xiang;Cao, Yong
以介孔结构的CeO 2为载体，以CO为脱氧剂，在无添加剂和温和的反应条件下，制备了一种用于硝基芳烃还原偶联合成各种芳香偶氮化合物的介孔结构的金（Au/meso-CeO 2）催化剂.
A facile and efficient catalytic system based on a mesostructured ceria-supported gold (Au/meso-CeO2) catalyst was developed for the synthesis of various aromatic azo compounds by the reductive coupling of the corresponding nitroaromatics, using CO as the sole deoxygenative reagent, under additive-free and mild reaction conditions.