Configuration interaction in the continuum states of molecules

Configuration interaction in the continuum states of molecules
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分子连续态中的构型相互作用

DOI:
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发表时间:
1968
期刊:
影响因子:
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通讯作者:
J. Bardsley
J. Bardsley
中科院分区:
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文献类型:
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作者:
J. Bardsley

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组态相互作用的理论进行了讨论有关的分子状态,有足够的能量,通过电子发射或预解离衰变。通过考虑电子发射的影响,发展了一种适用于极低能量下电子-分子碰撞的共振散射形式。通过对巴罗等人最近研究硒光谱的分析,证明了该理论在预解离中的应用。
The theory of configuration interaction is discussed in relation to molecular states which have sufficient energy to decay by electron emission or pre-dissociation. By considering the effects of electron emission a resonant scattering formalism is developed which is useful for electron-molecule collisions at very low energies. The application of the theory to pre-dissociation is demonstrated by an analysis of the recent study by Barrow et al. of the spectrum of selenium.