Thiazolium carbene catalysts for the fixation of CO2 onto amines
Thiazolium carbene catalysts for the fixation of CO2 onto amines
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DOI：
10.1039/c5cc08741d
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发表时间：
2016-01-01
影响因子：
4.9
通讯作者：
Dyson, Paul J.
中科院分区：
文献类型：
--
作者：
Das, Shoubhik;Bobbink, Felix D.;Dyson, Paul J.
The catalytic N-formylation and N-methylation of amines using CO2 as the carbon source represents a facile and sustainable approach for the synthesis of pharmaceuticals and natural products. Herein, we describe highly effective and inexpensive thiazolium carbene-based catalysts derived from vitamin B1 for the N-formylation and N-methylation of amines, using polymethylhydrosiloxane (PMHS) as a reducing agent, which operate under ambient conditions.
