In Situ Measurement of Composition in High-Temperature Solutions by X-Ray Fluorescence Spectrometry
In Situ Measurement of Composition in High-Temperature Solutions by X-Ray Fluorescence Spectrometry
复制标题
X 射线荧光光谱法原位测量高温溶液中的成分
DOI：
10.1143/jjap.39.5981
复制
发表时间：
2000
影响因子：
1.5
通讯作者：
K. Nakajima
中科院分区：
文献类型：
--
作者：
T. Ujihara;G. Sazaki;S. Miyashita;N. Usami;K. Nakajima
提出了一种基于X射线荧光光谱法的坩埚内高温溶液成分在线测量技术。用于该技术的样品保持器由对X射线透明的碳组成。使用本技术，测量镓溶液中锌的平衡组成。实验结果与Ga-Zn相图的液相线相吻合，证明了该方法的有效性。
We proposed an in situ technique based on X-ray fluorescence spectrometry to measure the composition of a high-temperature solution in a crucible. The sample holder for this technique was composed of carbon, which is transparent to X-rays. Using the present technique, equilibrium compositions of zinc in a gallium solution were measured. The results agreed well with the liquidus curve of the Ga–Zn phase diagram, and thus the validity of this technique was proved.