Nuclear Magnetic Resonance - Volume 45
Nuclear Magnetic Resonance - Volume 45
复制标题
核磁共振 - 第 45 卷
DOI：
10.1039/9781782624103-00096
复制
发表时间：
2016
期刊：
影响因子：
--
通讯作者：
Farnan I
中科院分区：
文献类型：
--
作者：
Farnan I
在世界范围内，许多核磁共振波谱仪的适应性提高了高分辨率液体核磁共振的核化学能力。在固态，“核化”MASNMR的出现允许部署高分辨率固态方法。介绍了安全获取含有放射性核素的液体、溶液和固体的NMR谱的协议。使用这些核磁共振方法作为一个重要的工具，在发展中的水性核燃料再处理和分区和嬗变战略，放射性核素在地圈的命运和运输和放射性核素在人体中的影响进行了说明。在固体方面，讨论了新型核燃料的发展和固体辐射损伤效应的量化。
The adaptation, worldwide, of a number of NMR spectrometers has increased nuclear chemistry capability in high-resolution liquid NMR. In the solid-state, the advent of ‘nuclearised’MASNMR allows the deployment of high-resolution solid-state methods. Protocols for safely acquiring NMR spectra of liquids, solutions and solids containing radionuclides are introduced. The use of these NMR methods as an essential tool in the development of aqueous nuclear fuel re-processing and partitioning and transmutation strategies, the fate and transport of radionuclides in the geosphere and the effect of radionuclides in the human body are described. In the solid-state, the development of new nuclear fuels and quantifying the effects of radiation damage in solids is discussed.