SYNTHESIS AND CRYSTAL-STRUCTURE OF [MNII(H3L)(L)MNIV][PF6]3 [H3L = N,N',N''-TRIS-(2S)-2-HYDROXYPROPYL-1,4,7-TRIAZACYCLONONANE] - A MIXED-VALENCE PENDANT-ARM MACROCYCLE DIMER IN WHICH THE LIGAND ADOPTS DIFFERENT ANGULAR GEOMETRIES AT THE 2 METAL CENTERS
SYNTHESIS AND CRYSTAL-STRUCTURE OF [MNII(H3L)(L)MNIV][PF6]3 [H3L = N,N',N''-TRIS-(2S)-2-HYDROXYPROPYL-1,4,7-TRIAZACYCLONONANE] - A MIXED-VALENCE PENDANT-ARM MACROCYCLE DIMER IN WHICH THE LIGAND ADOPTS DIFFERENT ANGULAR GEOMETRIES AT THE 2 METAL CENTERS
复制标题
DOI：
10.1039/c39910000402
复制
发表时间：
1991-03-15
影响因子：
--
通讯作者：
PEACOCK, RD
中科院分区：
文献类型：
--
作者：
BELAL, AA;FALLIS, I;PEACOCK, RD
N,N',N''-三(2S)-2-羟丙基-1,4,7-三氮杂环壬烷 (H3L) 与 MnCl2 在中性或微碱性条件下反应，得到 (Mn(II)(H3L)(L)Mn(IV)][PF6]3，一种混合价氢桥二聚体，其中 Mn(IV) 一半具有假八面体几何结构，Mn(II) 一半具有假八面体几何结构。三棱柱几何形状。
Reaction of N,N',N''-tris(2S)-2-hydroxypropyl-1,4,7-triazacyclononane (H3L) with MnCl2 in neutral or slightly basic conditions affords (Mn(II)(H3L)(L)Mn(IV)][PF6]3, a mixed-valence, hydrogen-bridged dimer in which the Mn(IV) half has pseudooctahedral geometry and the Mn(II) half has trigonal prismatic geometry.