Synthesis and electron holography studies of single crystalline nanostructures of clathrate-II phases K(x)Ge136 and Na(x)Si136.
Synthesis and electron holography studies of single crystalline nanostructures of clathrate-II phases K(x)Ge136 and Na(x)Si136.
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笼形II相K(x)Ge136和Na(x)Si136单晶纳米结构的合成和电子全息研究。
DOI：
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发表时间：
2011
影响因子：
15
通讯作者：
A. Guloy
中科院分区：
文献类型：
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作者：
P. Simon;Zhongjia Tang;W. Carrillo‐Cabrera;K. Chiong;Bodo Böhme;M. Baitinger;H. Lichte;Y. Grin;A. Guloy
由碱金属四氢萘在基于DTAC/AlCl（3）的离子液体中的分散体获得笼形物-II相K（x）Ge（136）和Na（x）Si（136）的结晶纳米尺寸颗粒，将其缓慢加热至120-180 °C。纳米颗粒是子弹形的，具有约40 nm宽和140-200 nm长的典型尺寸。详细的结构研究，使用高分辨率透射电子显微镜（HRTEM）和电子全息揭示的结晶度和致密的形态的笼形纳米棒。
Crystalline nanosized particles of clathrate-II phases K(x)Ge(136) and Na(x)Si(136) were obtained from a dispersion of alkali metal tetrelides in ionic liquids based on DTAC/AlCl(3), which were slowly heated to 120-180 °C. The nanoparticles are bullet-shaped with typical dimensions of about 40 nm in width and 140-200 nm in length. Detailed structure investigations using high-resolution transmission electron microscopy (HRTEM) and electron holography reveal the crystallinity and dense morphology of the clathrate nanorods.