Tetraethynylethene Molecular Scaffolding
Tetraethynylethene Molecular Scaffolding
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四乙炔乙烯分子支架
DOI：
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发表时间：
1997
期刊：
影响因子：
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通讯作者：
F. Diederich
中科院分区：
文献类型：
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作者：
R. Tykwinski;F. Diederich
四乙炔基乙烯（3，4-二乙炔基己-3-烯-1，5-二炔，C10 H4）及其差异保护的衍生物是用于富碳分子支架的通用构件。它们已被应用于制备全乙炔化的脱氢轮烯，扩展的径向烯，聚（三乙炔），有机金属的σ-乙炔化物物种，和具有有趣的非线性光学性质的供体/受体功能化的发色团。本文介绍了四乙炔基乙烯及其衍生物的合成，并将其加工成新型的线性或交叉共轭发色团和功能性富碳纳米材料。
Tetraethynylethene (3,4-diethynylhex-3-ene-1,5-diyne, C10H4) and its differentially protected derivatives are versatile building blocks for carbon-rich molecular scaffolding. They have been applied to the preparation of perethynylated dehydroannulenes, expanded radialenes, poly(triacetylenes), organometallic σ-acetylide species, and donor/acceptor-functionalized chromophores with interesting nonlinear optical properties. This article gives an account of the synthesis of tetraethynylethene and its derivatives as well as their elaboration into novel linearly or cross-conjugated chromophores and functional carbon-rich nanomaterials.