A new strategy to construct metal–organic frameworks with ultrahigh chemical stability
A new strategy to construct metal–organic frameworks with ultrahigh chemical stability
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DOI：
10.1039/c4ce01218f
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发表时间：
2014-08
期刊：
影响因子：
3.1
通讯作者：
Lei Xu;Jintao Wang;Yan Xu;Zaiyong Zhang;P. Lu;Min Fang;Shunli Li;P. Sun;Hongke Liu
中科院分区：
文献类型：
--
作者：
Lei Xu;Jintao Wang;Yan Xu;Zaiyong Zhang;P. Lu;Min Fang;Shunli Li;P. Sun;Hongke Liu
A novel two-dimensional metal–organic framework has been constructed from Fe3+ and meso-tetra(4-imidazoyl)porphyrin, which can remain in saturated (~27.5 M) NaOH solution for a week. To the best of our knowledge, this is the first report of a MOF that is stable in saturated NaOH solution. The utilization of an imidazolyl-based porphyrin ligand and a high-valence metal is a new and promising strategy for constructing porphyrinic MOFs with ultra-high stability.
