BASIC PRINCIPLES OF THE CIP-SYSTEM AND PROPOSALS FOR A REVISION
BASIC PRINCIPLES OF THE CIP-SYSTEM AND PROPOSALS FOR A REVISION
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DOI：
10.1002/anie.198205671
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发表时间：
1982-01-01
期刊：
影响因子：
--
通讯作者：
HELMCHEN, G
中科院分区：
文献类型：
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作者：
PRELOG, V;HELMCHEN, G
《从立体异构体的构型表示法到立体化学的概念基础》是一场讲座的题目。先生。第12号(1975)179]，其中按时间顺序和字母顺序排列的CIP三人组的第三名成员讨论了CIP系统的历史。在此期间积累的经验，特别是卡恩、英戈尔德和普雷洛格在1966年描述的教计算机使用该系统的努力表明，它的某些方面必须得到更严格的表述，而另一些方面必须加以修改。关于立体异构体(和立体立体)的问题，以前主要是以务实的方式处理的，现在以系统的方式进行讨论。
“From Configurational Notation of Stereoisomers to the Conceptual Basis of Stereochemistry” is the title of a lecture [V. Prelog, ACS Symp. Ser. No. 12 (1975) 179] in which the chronologically and alphabetically third member of the CIP‐triumvirate discusses the history of the CIP‐system. The experience accumulated in the meantime, particularly the efforts to teach computers to use the system as described in 1966 by Cahn, Ingold and Prelog, has shown that certain of its aspects must be more strictly formulated and others modified. Questions dealing with stereoisomers (and stereotopicity), which previously have been treated predominantly in a pragmatic manner, are now discussed in a systematic way.