Giant N-heterocyclic carbene-containing macrocycles for cobalt-catalysed hydroboration of alkynes
Giant N-heterocyclic carbene-containing macrocycles for cobalt-catalysed hydroboration of alkynes
复制标题
用于钴催化炔烃硼氢化反应的巨型含氮杂环卡宾大环化合物
DOI：
10.1039/d2cc02815h
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发表时间：
2022
影响因子：
4.9
通讯作者：
Zhang, Guoqi
中科院分区：
文献类型：
--
作者：
Zhang, Guoqi
合成了一系列大于德克萨斯大小的含氮杂环卡宾的有机大环化合物，并对其结构进行了表征。在Co-NHC催化下，该大环化合物具有良好的立体选择性和区域选择性。
Giant N-heterocyclic carbene-containing organic macrocycles larger than “Texas-sized” molecular boxes have been synthesized and structurally characterized. The new macrocycles were employed for the Co-NHC promoted syn-selective hydroboration of alkynes with good stereo- and regioselectivity.