Nickel-catalyzed reactions of silacyclobutanes with aldehydes: Ring opening and ring expansion reaction
Nickel-catalyzed reactions of silacyclobutanes with aldehydes: Ring opening and ring expansion reaction
复制标题
DOI：
10.1021/ol0527577
复制
发表时间：
2006-02-02
期刊：
影响因子：
5.2
通讯作者：
Oshima, K
中科院分区：
文献类型：
--
作者：
Hirano, K;Yorimitsu, H;Oshima, K
[图表]硅杂环丁烷与醛的镍催化开环反应得到相应的烷氧基烯丙基硅烷。相反，苯并硅杂环丁烯与醛在镍催化下发生扩环反应，得到氧杂硅杂环己烯。
[GRAPHICS]The nickel-catalyzed ring opening reaction of silacyclobutanes with aldehydes affords the corresponding alkoxyallylsilanes. In contrast, the ring expansion reaction of benzosilacyclobutene with aldehydes occurs under nickel catalysis to give oxasilacyclohexenes.