Pd/TEMPO-catalyzed electrooxidative synthesis of biaryls from arylboronic acids or arylboronic esters
Pd/TEMPO-catalyzed electrooxidative synthesis of biaryls from arylboronic acids or arylboronic esters
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DOI：
10.1016/j.tet.2009.08.004
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发表时间：
2009-10-03
期刊：
影响因子：
2.1
通讯作者：
Tanaka, Hideo
中科院分区：
文献类型：
--
作者：
Mitsudo, Koichi;Shiraga, Takuya;Tanaka, Hideo
介绍了一种由芳基硼酸或芳基硼酸酯合成联芳基化合物的简便电氧化方法。在催化量的Pd（OAC）（2）和克里思存在下，芳基硼酸或芳基硼酸酯的电氧化以中等至优异的产率得到相应的联芳基化合物。(C)2009爱思唯尔有限公司保留所有权利。
A facile electrooxidative method for synthesizing biaryls from arylboronic acids or arylboronic esters is described. In the presence of a catalytic amount of Pd(OAC)(2) and TEMPO, the electrooxidation of arylboronic acids or arylboronates gave the corresponding biaryls in moderate to excellent yields. (C) 2009 Elsevier Ltd. All rights reserved.