Borataalkene Hydrofunctionalization Reactions
Borataalkene Hydrofunctionalization Reactions
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DOI：
10.1021/acs.organomet.1c00261
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发表时间：
2021-06-11
期刊：
影响因子：
2.8
通讯作者：
Martin, Caleb D.
中科院分区：
文献类型：
--
作者：
Bartholome, Tyler A.;Martinez, Jesse J.;Martin, Caleb D.
烯烃的氢官能化反应是一类基本的反应，然而，含B=C键的类似反应几乎还未被探索。这项工作发现了一系列与9-硼杂菲阴离子的B=C氢官能化反应，包括加氢烷基化、加氢芳化、加氢炔化、加氢胺化、加氢烷氧基化和水合。独特的反应性代表了除了合成化学家的工具箱，以获得官能化的四配位硼酸盐。
The hydrofunctionalization of alkenes is a foundational class of reactions; however, the analogous reactions for B=C bond-containing species have been virtually unexplored. This work unearths a range of B=C hydrofunctionalization reactions with the 9-borataphenanthrene anion, including hydroalkylation, hydroarylation, hydroalkynylation, hydroamination, hydroalkoxylation, and hydration. The unique reactivity represents an addition to the synthetic chemist's toolbox to access functionalized tetracoordinate borates.