Peripherally cyclometalated iridium complexes of dipyridylporphyrin
Peripherally cyclometalated iridium complexes of dipyridylporphyrin
复制标题
二吡啶基卟啉的外围环金属化铱配合物
DOI：
10.1039/c1dt10246j
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发表时间：
2011
期刊：
影响因子：
--
通讯作者：
H.
中科院分区：
文献类型：
--
作者：
Yoshida;K.;Nakashima;T.;Yamaguchi;S.;Osuka;A.;Shinokubo;H.
以二吡啶卟啉为原料合成了两种新型卟啉螯合物。其中一个配合物在聚合物配位模式下在铱中心有一个刘易斯酸位点。另一个配合物采用面配位，这在苯基钳形配合物中很少观察到。
Two types of novel iridium pincer complexes bearing a porphyrin backbone were synthesized and characterized from dipyridylporphyrin. One of the complexes has a Lewis acidic site on the iridium center in the mer-coordination mode. The other complex takes the fac-coordination, which is rarely observed in benzene-based pincer complexes.